منابع مشابه
Radiolysis of Liquid Propane: non-Radical Reactions
The yields of ionic and excited molecule reactions in y-radiolysis of liquid propane from 35 to -130C have been assessed by isotopic analysis of C3Hs-l-C3Ds+Oz and CH3CD2CH3 -1-02 mixtures. From a comparison with gas phase data the following conclusions are reached for the gas to liquid phase change: (a) the ionic decomposition yield rlecreases by :5 69 %, (b) the net excited molecule decomposi...
متن کاملRadiolysis of Liquid Propane: Radical Reactions
The radical reactions in the liquid phase y-radiolysis of propane have been studied from -130 to 35°C and compared with the gas-phase radiolysis at 35°C. Oxygen was used as a scavenger 10 separate thermal radical yields, and effects· of phase and temperature on the radical yields were assessed. The gas-liquid phase change (a) decreases total decomposition by about 14 %, (b) increMCs disproporti...
متن کاملSolution Phenomena in Liquid Ammonia
An extended discussion of solution phenomena in anhydrous liquid ammonia is presented. The solvent properties of ammonia for various classes of compounds is discussed in terms of its hydrogen bonding ability, moderate dielectric constant, elatively high basicity, and high dipole moment. In general, ammonia is a better solvent than water for covalent molecules, but a poor solvent for ionic speci...
متن کاملHydrogen generation by electrolysis of liquid ammonia.
Hydrogen gas is generated by the electrolysis of liquid ammonia which has high hydrogen capacity of 17.8 mass%. The metal amides are used as supporting electrolytes to dissolve the amide ion in liquid ammonia. The results presented here indicate that liquid ammonia is promising as an energy medium for hydrogen storage and generation.
متن کاملThe Ammonolysis of Esters in Liquid Ammonia
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ژورنال
عنوان ژورنال: NIPPON KAGAKU KAISHI
سال: 1972
ISSN: 2185-0925,0369-4577
DOI: 10.1246/nikkashi.1972.1591